X-ray luminescence in undoped and bismuth-doped single crystal hybrid lead halide perovskites

Aozhen Xie; Tien Hoa Nguyen; Chathuranga Hettiarachchi; Marcin E. Witkowski; Winicjusz Drozdowski; Muhammad Danang Birowosuto; Hong Wang; Cuong Dang

doi:10.1117/12.2509345

26 February 2019 X-ray luminescence in undoped and bismuth-doped single crystal hybrid lead halide perovskites

Aozhen Xie, Tien Hoa Nguyen, Chathuranga Hettiarachchi, Marcin E. Witkowski, Winicjusz Drozdowski, Muhammad Danang Birowosuto, Hong Wang, Cuong Dang

Author Affiliations +

Proceedings Volume 10912, Physics and Simulation of Optoelectronic Devices XXVII; 109121G (2019) https://doi.org/10.1117/12.2509345
Event: SPIE OPTO, 2019, San Francisco, California, United States

Abstract

Systematic investigation of temperature-dependence on thermal quenching of X-ray luminescence (XL) from various single perovskite crystals was carried out. In the family of methylammonium lead halide perovskites (MAPbX₃, MA = methylammonium, X= Cl, Br or I), the quenching temperature of XL decreases from Cl to I. According to our analysis, such behavior is strongly affected by their corresponding decrease of thermal activation energy ▵E_q from 53 ± 3 to 6 ± 1 meV. Different concentrations of Bi³⁺-doped MAPbBr3 are also prepared and both four-point probe measurement and X-ray thermoluminescence (TL) confirms the successful doping. When we dope MAPbBr3 with Bi³⁺, Γ₀/Γ_v increases to 78 ± 18 for crystal with Bi/Pb ratio of 1/10 in precursor solution.

Citation Download Citation

Aozhen Xie, Tien Hoa Nguyen, Chathuranga Hettiarachchi, Marcin E. Witkowski, Winicjusz Drozdowski, Muhammad Danang Birowosuto, Hong Wang, and Cuong Dang "X-ray luminescence in undoped and bismuth-doped single crystal hybrid lead halide perovskites", Proc. SPIE 10912, Physics and Simulation of Optoelectronic Devices XXVII, 109121G (26 February 2019); https://doi.org/10.1117/12.2509345

ACCESS THE FULL ARTICLE

INSTITUTIONAL
Select your institution to access the SPIE Digital Library.

SELECT YOUR INSTITUTION

PERSONAL
Sign in with your SPIE account to access your personal subscriptions or to use specific features such as save to my library, sign up for alerts, save searches, etc.

PERSONAL SIGN IN

No SPIE Account? Create one

PURCHASE THIS CONTENT

SUBSCRIBE TO DIGITAL LIBRARY

50 downloads per 1-year subscription

Members: $195

Non-members: $335 ADD TO CART

25 downloads per 1 - year subscription

Members: $145

Non-members: $250 ADD TO CART

PURCHASE SINGLE ARTICLE

Includes PDF, HTML & Video, when available