Ionization-detected rotational coherence spectroscopy of mass selected clusters

A. H. Bahnmaier; Alan G. Joly; John M. Price; Douglas Ray

doi:10.1117/12.220846

18 September 1995 Ionization-detected rotational coherence spectroscopy of mass selected clusters

A. H. Bahnmaier, Alan G. Joly, John M. Price, Douglas Ray

Proceedings Volume 2548, Laser Techniques for State-Selected and State-to-State Chemistry III; (1995) https://doi.org/10.1117/12.220846
Event: SPIE's 1995 International Symposium on Optical Science, Engineering, and Instrumentation, 1995, San Diego, CA, United States

Abstract

We report the first application of a multiphoton ionization based, mass selective implementation of psec time resolved rotational coherence spectroscopy (RCS) to molecular clusters. This implementation of rotational coherence spectroscopy retains all of the advantages of fluorescence based implementations of RCS and also allows determination of the moments of inertia of molecular species which cannot be size selected via excitation energy or which do not fluoresce. The method is described and rotational coherence transients obtained are presented.

Citation Download Citation

A. H. Bahnmaier, Alan G. Joly, John M. Price, and Douglas Ray "Ionization-detected rotational coherence spectroscopy of mass selected clusters", Proc. SPIE 2548, Laser Techniques for State-Selected and State-to-State Chemistry III, (18 September 1995); https://doi.org/10.1117/12.220846

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