Accessing novel ion acceleration mechanisms, such as Radiation Pressure Acceleration (RPA), is a promising route to generate high energy beams of both light and heavy ions [1]. In particular, the Light Sail (LS) regime predicts high efficiency, mono-energetic beams and can be accessed with currently available high power laser facilities with the use of ultra-thin foils and circular polarisation [2-4]. In recent experiments at the GEMINI laser facility (RAL, UK), target bulk (carbon) ions were favourably accelerated in the LS-RPA regime up to 33MeV/nucleon at an optimal carbon foil thickness of 15nm, whereas protons only reached energies of 18 MeV. This result, which differs from what is typically observed in laser-solid interactions, where protons are always accelerated more efficiently than heavier ions, is interpreted with the support of multi-dimensional Particle in Cell (PIC) simulations. While the 40fs pulse was temporally cleaned by a double plasma mirror arrangement to increase the laser contrast to 10-14 at the ns timescale, it is shown that the limited preceding laser fluence incident on the target on the ps scale causes target expansion, with protons, being lighter, escaping from the interaction region. This leaves a pre-dominantly carbon plasma which, for circular polarization, is accelerated by RPA, with proton energies determined instead by plasma expansion and sheath effects. It is shown through simulations that controlling the laser temporal profile and plasma mirror activation opens up a promising route for controlling which ion species is preferentially accelerated in the RPA regime. This has particular importance as <1PW systems are coming online currently where these accelerations will begin to inherently dominate, and the preceding laser intensity will need to be suitably controlled.
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