This conference presentation was prepared for the Plasmonics: Design, Materials, Fabrication, Characterization, and Applications XX conference at SPIE Optics + Photonics 2022.
Large-area plasmonic metasurfaces have attracted interest as potential tools for a wide range of applications, from colorchanging glass to improved efficiency of solar cells. These potential applications necessitate the capability to fabricate such surfaces at scale. One potential approach to resolve this issue is to use nanoimprint lithography to mold a metasurface structure and then use chemically synthesized nanoparticles as the metallic elements. By combining aluminum nanoparticles with electrophoretic deposition, a low-cost method of scalable fabrication could be achieved.
Substantial effort has been invested in generating narrow bandwidth visible colors from metasurfaces using a wide variety of geometries and materials. In this work we continue these explorations and demonstrate how a combination of a plasmonic Fano resonance and a Bragg reflector can contribute to the generation of narrowband visible colors. We demonstrate active tuning of these colors by stretching the array in the x- and y- directions and the reflector in z- to shift the colorimetric response of both elements. The combination of these two types of photonic structures allows for substantially increased flexibility in design and color-space tuning. Additionally, by fabricating these structures at scale, this methodology could prove useful towards the manufacture of agile metasurface color pixels
Nanoscale sensing arrays utilizing the unique properties of the optical protein bacteriorhodopsin and colloidal semiconductor quantum dots are being developed to detect minute concentrations of airborne toxins. This paper describes an innovative method to activate bacteriorhodopsin-based sensors with the optical output of quantum dots, producing a measurable electrical response from the protein. The ability of quantum dots to activate nanoscale regions on bacteriorhodopsin-based electrodes allows sub-micron sensing arrays to be created due to the ability to activate site-specific regions on the array. A novel method to modulate the sensor's electrical output to obtain both "on" and "off" states is also achieved utilizing the fluorescence resonance energy transfer characteristics of a bacteriorhodopsin/quantum dot system. Apart from applying this technology to toxin detection arrays, the ability to readily manipulate the protein's electrical and optical characteristics could have implications in other areas of nanobiotronics.
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