Periodic wavelength-scale surface patterns have long been used in the context of lasing and spontaneous emission to enhance emission by light trapping (distributed Bragg resonances). Buried within these well-known devices, however, are theoretical mysteries that are still being unravelled. A periodic surface grating actually creates a continuum of resonant modes, so what determines which single mode (if any) lases? Technically, what determines the stability of a periodic lasing mode: is it only the finite size of a surface that allows single-mode lasing, or can it arise for arbitrarily large structures? More generally, if one continuously deforms an unpatterned surface to maximize light emission, how is the symmetry broken and what optimal structures arise? We address these questions by combining new computational techniques for modeling and large-scale optimization of incoherent emission and lasing with new analytical results arising from perturbation and stability theory.
Various scatterers such as rough surfaces or nanostructures are typically used to enhance the low efficiency of Raman spectroscopy (surface-enhanced Raman scattering). In this work, we find fundamental upper bounds on the Raman enhancement for arbitrary-shaped scatterers, depending only on its material constants and the separation distance from the molecule. According to our metric, silver is optimal in visible wavelengths while aluminum is better in the near-UV region. Our general analytical bound scales as the volume of the scatterer and the inverse sixth power of the distance to the active molecule. For periodic scatterers, a second bound with surface-area scaling is presented. Simple geometries such as spheres and bowties are shown to fall short of the bounds. However, using topology optimization based inverse design, we obtain surprising structures maximizing the Raman enhancement. These optimization results shed light to what extent our bounds are achievable.
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