Because of its ease of growth and large electro-optic effect, lithium niobate is the preferred choice for Q-switching
mobile lasers. Temperature-induced pyro-electric charges however may lead to premature lasing. We manufactured and
characterized temperature-stable LN Q-switch. A thermo-chemical anneal was performed creating a conductive material
layer 0.5mm thick with increased conductivity. While this increases optical insertion loss by a few percent, this is
tolerable in high gain lasers. We present details of treatment, the surface charge creation and dissipation mechanism and
the setup used to assess the cold-performance used to demonstrate improved charge dissipation when compared to
untreated crystals.
Lithium niobate (LN) is commonly used as an electro optic (EO) Q-switch material in infrared targeting lasers because
of its relatively low voltage requirements and low cost compared to other crystals. A common challenge is maintaining
good performance at the sub-freezing temperatures often experienced during flight. Dropping to low temperature causes
a pyro-electric charge buildup on the optical faces that leads to birefringence non-uniformity and depolarization resulting
in poor hold-off and premature lasing. The most common solution has been to use radioactive americium to ionize the
air around the crystal and bleed off the charge, but the radioactive material requires handling and disposal procedures
that can be problematic. We have developed a superior solution that is now being implemented by multiple defense
system suppliers. By applying a low level thermo-chemical reduction to the LN crystal optical faces we induce a small
conductivity that allows pyro-charges to dissipate. As the material gets more heavily treated, the capacity to dissipate
charges improves, but the corresponding optical absorption also increases, causing insertion loss. Even though typical
high gain targeting laser systems can tolerate a few percent of added loss, the thermo-chemical processing needs to be
carefully optimized. We describe the results of our process optimization to minimize the insertion loss while still giving
effective charge dissipation. Treatment is performed at temperatures below 500°C and a conductivity layer less than
0.5mm in depth is created that is uniform across the optical aperture. Because the conductivity is thermally activated, the
charge dissipation is less effective at low temperature, and characterization needs to be performed at cold temperatures.
The trade-off between optical insertion loss and potential depolarization due to low temperature operation is discussed
and experimental results on the temperature dependence of the dissipation time and the optical loss are reported.
The ability to achieve high quality periodic poling in lithium niobate (LN) has allowed quasi-phase-matching to be used for second-order nonlinear optics, leading to experimental demonstration of efficient optical frequency generation throughout its wide transparency range (0.35-4.5 microns). Applications of congruent lithium niobate involving visible or ultraviolet wavelengths are limited to low power or high temperature operation due to the effects of photorefractive damage (PRD) and green-induced infrared absorption (GRIIRA). The standard methods of suppressing PRD include doping with 5 mol-% MgO or ZnO and varying crystal stoichiometry. More recent methods employ a combination of lower doping level and near-stoichiometric composition. We use vapor transport equilibration (VTE) and significantly lower MgO doping (<0.5% in the melt) to obtain near-stoichiometric PRD-resistant crystals with improved parameters for periodic poling compared to the commercially available 5% MgO-doped congruent crystals. An efficient process for periodic poling at room temperature using baked photoresist as a patterned dielectric on one crystal surface with LiCl-solution electrodes was developed for periods as short as 8.3 microns for 0.5% and 7 microns for 0.3% MgO-doped VTE:LN. The quality of periodic poling improves as the MgO concentration is lowered. Stable second harmonic generation of 1.3-W continuous-wave 532-nm radiation was observed near room temperature (43 degrees Celsius, as determined by the phase matching condition) with no sign of degradation in a 1.5-cm long crystal of 0.3-% MgO-doped VTE:LN periodically poled with a period of 7.06 microns.
We use a combination of vapor transport equilibration and moderate MgO doping (≤1%) to explore near-stoichiometric damage resistant lithium niobate crystals with improved properties for periodic poling and annealed-proton-exchange waveguide fabrication compared to the commercially available 5-mol% MgO-doped crystals. High damage resistance, measured by the saturated space-charge field generated in the crystal by 514 nm radiation, was obtained for all MgO doping concentrations (0.3, 0.5 and 1%) with appropriate equilibration. Green-induced infrared absorption was also measured in the 0.3-% doped crystal and was below the detection limit. Dispersion in the region 460-1550 nm was measured. Periodic poling was performed using LiCl solution electrodes. Poling quality improves with lowering MgO concentration. Waveguides for frequency doubling of 1550 nm were fabricated in the 1% doped crystal with losses as low as 0.4 dB/cm and normalized efficiency of ~10%/Wcm2.
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