Quartz Enhanced Photothermal Spectroscopy (QEPTS) is a technique, which enables developing gas sensors characterized by a broadband operational range and superb sensitivity. QEPTS relies on the thermoelastic effect induced by the illumination of the Quartz Tunning Fork (QTF) with a modulated laser radiation, which generates a piezoelectric signal. QTF excitation can occur at any wavelength, which is impossible to observe in e.g. semiconductor detectors. The sub-dollar cost of a QTF delivers simultaneously broadband and sensitive detection capability and significantly reduced costs of the sensor. Furthermore, as in majority of laser-based sensors, the sensitivity of QEPTS-based systems can be easily enhanced by increasing laser-gas interaction path length. This is typically realized by using multipass cells (MPCs), which significantly increase the sensor’s complexity and decrease its robustness. Instead of using MPCs, an Antiresonant Hollow-Core Fiber (ARHCF), designed for light transmission in more than one spectral band can be used as a long gas absorption cell, leading to the increase in the sensor’s performance while keeping its design simple. Here, we present a sensor utilizing a combination of an ARHCF-based absorption cell and the QEPTS. In the developed system the gas-filled ARHCF substitutes an MPC. The spectroscopic signal analysis relies on the use of a simple QTF with a resonance frequency of 32.744 kHz connected with a self-made, low-noise amplifier and an addition of a wavelength modulation spectroscopy – based signal retrieval scheme for sensor’s performance enhancement. The sensor enables simultaneous detection of acetylene and methane at parts-per-million by volume level sensitivity, targeting their absorption lines in the near- and mid-infrared. The results confirm excellent suitability of the ARHCF-aided QEPTS sensors for being employed as a versatile gas detectors.
This research was funded by Narodowe Centrum Nauki (NCN), grant number UMO-2018/30/Q/ST3/00809.
We present the results of modelling of pressure-driven gas flow in a 14.7 meters long nodeless Antiresonant Hollow Core Fiber (ARHCF) for predicting the gas exchange time in the ARHCF-based laser absorption spectroscopy measurement systems. The implemented physical model is based on the Navier-Stokes equations for laminar flow. The tunable diode laser absorption spectroscopy has been used for determining experimentally the ARHCF gas filling time. The obtained results confirmed the requirement for more complex geometric models to properly predict the core filling time of nodeless ARHCFs than a simple, single-channel approach, which can be used effectively for gap-less ARHCFs.
In this work, we present simultaneous and sensitive detection of methane and ethane at ~3.34 µm using a 15-meteres long self-fabricated silica ARHCF and Wavelength Modulation Spectroscopy technique. The ARHCF was filled with a mixture of 10 ppmv and 20 ppmv ethane and methane, respectively via air-tight housings placed at both fiber end-facets. The gas molecules were excited using a self-built continuous wave Difference Frequency Generation source which radiation was coupled into the gas-filled ARHCF. The ARHCF-aided gas sensor reached a minimum detection limit at parts-per-billion by volume level, confirming the suitability of the proposed approach for trace-gas sensing.
We present a proof-of-concept of the ARHCF-assisted gas molecules detection setup applying a non-wavelength modulation differential optical absorption spectroscopy (DOAS) technique to reduce an intermodal interferences effect and the compensation of changes in laser beam propagation parameters through ARHCF air-core. Toggled intensities of two air-core propagated laser beams have closely spaced wavelengths, while only one coinciding with targeted absorption line of acetylene at 1532.83 nm (~6524 cm-1). The difference in detected light intensities is used to determine a targeted gas concentration. Self-designed boxcar average unit allowed to 50 000 times/sec signals averaging, providing a minimal detection limit equal to 2.7 ppmv at 10s integration time.
Detection of Nitric Oxide at 5.26 µm is performed using photothermal interferometry and a 25 cm-long antiresonant hollow-core fiber as an absorption cell, reaching a minimum detection limit of 11 ppb for 144 seconds averaging. The proposed configuration shows the full potential of combining novel hollow-core fibers with the photothermal detection techniques, which allows separating the pump and the probe part of the sensor.
One of the main challenges of laser-based gas sensingis the development of sensors delivering simultaneously high sensitivity, selectivity, fast-response time and non-complex design. Mostly, the detection capability of such sensors depends on the interaction path length between the laser light and the measured gas. Hence, long optical paths are highly desired for e.g. low-concentration gas sensing. Our proposal is to use Antiresonant Hollow-Core Fibers (ARHCFs), which filled with the target gas mixture form absorption cells with potentially any length, delivering low-volume, long and versatile optical paths within the sensor configuration. Currently, the ARHCF core is filled with the target gas via specially designed bulk-optics-based cells placed at the fiber’s ends. This solution provides relatively fast fiber core filling time, however being only efficient while an overpressure is used to force the gas flow through the core, not the diffusion. Therefore, searching for alternative ways of fiber filling with the target gas is necessary. We propose a method of processing the fiber structure using a femtosecond laser allowing for non-invasive accessing the fiber core for more efficient and faster gas diffusion into it through the fabricated microchannels. The fiber structure modification was optimized in a way that does not introduce any unwanted damage of the fiber e.g. cracks on the glass parts or cladding capillaries. The performed experiments have indicated that the laser-processing of the ARHCF structure introduces negligible transmission loss regardless of the number of fabricated microchannels and their length (0.2dB loss for 25 microchannels), confirming the proposed method suitability.
Due to its high toxicity, monitoring of hydrogen sulfide (H2S) concentration is essential in many industrial sites (such as natural gas extraction sites, petroleum refineries, geothermal power plants, or waste water treatment facilities), which require sub-parts-per-million sensitivities. We report on a quantum cascade laser-based spectroscopic system for detection of H2S in the midinfrared at ∼7.2 μm. We present a sensor design utilizing Herriott multipass cell and a wavelength modulation spectroscopy to achieve a detection limit of 140 parts per billion for 1-s integration time.
In this paper we present a dual-wavelength fiber mode-locked laser based on CVD-graphene saturable absorber (SA). The laser setup is based on two ring cavities connected by a common branch with a graphene SA. As a gain media erbium (Er) and thulium (Tm) doped active fiber were used. The laser generate optical pulses centered at 1558.5 nm and 1937 nm. The repetition rates and pulse durations were of 23.2 MHz, 16.42 MHz and 0.95 ps, 1.03 ps for the solitons generated in Er- and Tm-doped cavities, respectively.
We present a single frequency, stable, narrow linewidth, miniature laser sources operating at 532 nm (or 1064 nm) based on a monolithic resonators. Such resonators utilize birefringent filters formed by YVO4 beam displacer and KTP or YVO4 crystals to force single frequency operation at 532 nm or 1064 nm, respectively. In both configurations Nd:YVO4 gain crystal is used. The resonators dimensions are 1x1x10.5 mm3 and 1x1x8.5 mm3 for green and infrared configurations, respectively. Presented laser devices, with total dimensions of 40x52x120 mm3, are fully equipped with driving electronics, pump diode, optical and mechanical components. The highly integrated (36x15x65 mm3) low noise driving electronics with implemented digital PID controller was designed. It provides pump current and resonator temperature stability of ±30 μA@650 mA and ±0,003ºC, respectively. The laser parameters can be set and monitored via the USB interface by external application. The developed laser construction is universal. Hence, the other wavelengths can be obtained only by replacing the monolithic resonator. The optical output powers in single frequency regime was at the level of 42 mW@532 nm and 0.5 W@1064 nm with the long-term fluctuations of ±0.85 %. The linewidth and the passive frequency stability under the free running conditions were Δν < 100 kHz and 3⋅10-9@1 s integration time, respectively. The total electrical power supply consumption of laser module was only 4 W. Presented compact, single frequency laser operating at 532 nm and 1064 nm may be used as an excellent source for laser vibrometry, interferometry or seed laser for fiber amplifiers.
We present a method of generating mid-IR radiation by means of nonlinear difference frequency generation (DFG) effects occurring in periodically polled lithium niobate (PPLN) crystals using an all-fiber dual-wavelength amplifier. The presented mid-IR laser source incorporates an unique double-clad (DC) Erbium and Ytterbium (Er-Yb) doped amplifier stage capable of simultaneous amplification of both wavelengths required in the DFG process - 1064 nm and 1550 nm. The amplifier delivered more than 23.7 dB and 14.4 dB of amplification for 1550 nm and 1064 nm wavelength, low power, off-the-shelf, fiber pigtailed, distributed feedback (DFB) laser diodes, respectively. The dual-wavelength amplifier parameters crucial for the DFG process were investigated, including long-term power and polarization instabilities and optical spectrum characteristics of both amplified wavelengths. The DFG setup used a single collimator radiation delivery scheme and an 40 mm long MgO doped PPLN crystal. In effect the DFG source was capable of generating 1.14 mW of radiation centered around 3.4 μm. The overall performance of the mid-IR source was elaborated by performing sensitive Tunable Diode Laser Absorption Spectroscopy (TDLAS) detection of methane (CH4) in ambient air on an free-space optical path-length of 8 m. The measured detection limit of the sensor was 26 ppbv with a 1σ SNR of 69.
In this work we present our results on supercontinuum (SC) generation using a photonic crystal fiber (PCF) fabricated from lead-bismuth-gallium-oxide glass (PBG-08). Due to high refractive index, high nonlinearity and high transmittance, the PBG-08 glass-based fibers seem to be excellent media for broad supercontinuum generation in the infrared spectral region. In our experiment, a short-length piece of PCF (6 cm) is pumped by a femtosecond fiber laser system, delivering 540 fs pulses at 60 MHz repetition rate and 2.75 W of maximum average power. This compact and cost-effective system allows to generate supercontinuum spanning from 900 to 2400 nm.
The development of a continuous wave (CW), thermoelectrically cooled (TEC), distributed feedback (DFB) laser diode
based spectroscopic trace-gas sensor for ultra sensitive and selective ethane (C2H6) concentration measurements is reported. The sensor platform used tunable laser diode absorption spectroscopy (TDLAS) and wavelength modulation spectroscopy (WMS) as the detection technique. TDLAS was performed with an ultra-compact 57.6 m effective optical path length innovative spherical multipass cell capable of 459 passes between two mirrors separated by 12.5 cm. For an interference free C2H6 absorption line located at 2976.8 cm-1 a 1σ minimum detection limit of 130 pptv with a 1 second lock-in amplifier time constant was achieved.
KEYWORDS: Signal processing, Heterodyning, Digital signal processing, Semiconductor lasers, Signal detection, Laser applications, Fiber lasers, Electronics, Light scattering, Photodetectors
For the last few years we were elaborating the laser-fiber vibrometer working at 1550 nm. Our main stress was directed towards different aspects of research: analysis of scattered light, efficient photodetection, optimization of the fiber-free space interfaces and signal processing. As a consequence we proposed the idea of a multichannel fiber vibrometer based on well developed telecommunication technique – Wavelength Division Multiplexing (WDM). One of the most important parts of a fiber-laser vibrometer is demodulation electronic section. The distortion, nonlinearity, offset and added noise of measured signal come from electronic circuits and they have direct influence on finale measuring results. We present the results of finished project “Developing novel laser-fiber monitoring technologies to prevent environmental hazards from vibrating objects” where we have constructed a 4-channel WDM laser-fiber vibrometer.
In this work we present a new design of Er/Yb co-doped fiber amplifier with controlled amplified spontaneous emission
(ASE) at 1 μm. The Yb-ASE is controlled by stimulating a laser emission at 1064 nm in the amplifier, by providing
a positive 1 μm signal feedback loop. The results were discussed and compared to a conventional amplifier setup without
1 μm ASE control. We have shown, that applying a 1064 nm signal loop in an Er/Yb amplifier can increase the output
power at 1550 nm and provide stable operation without parasitic lasing at 1 μm.
KEYWORDS: Optical amplifiers, Semiconductor lasers, High power fiber amplifiers, High power lasers, Fiber amplifiers, Oscillators, Amplifiers, Fiber lasers, Laser applications, Cooling systems
In this work we present a high-power laser source developed in Master Oscillator Power Amplifier (MOPA)
configuration. Presented MOPA source consists of three amplifying stages: pre-amplifier based on erbium-doped fiber,
medium-power stage based on double-clad Er/Yb co-doped fiber and the power stage, based on Er/Yb co-doped doubleclad
LMA fiber. Whole system is set up in All-In-Fiber technique, without any bulk, free-space optical elements. It
provides over 20W of output power in the eye-safe 1550 nm band.
The WDM fiber transmission technique was used to measure vibration parameters of four points of a vibrating object.
The 4-independent laser diodes form a WDM system according to the rule 'one wavelength-one analyzed point'.
Keywords: laser Doppler vibrometry, fibre vibrometry, heterodyne detection, multichannel vibrometry.
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