SF6 gas sensor is developed to measure SF6 gas at different concentrations mixed with N2 based on mid-IR absorption of SF6 at a wavelength of ~10.6 μm. An optical bandpass filter of ~10.6 μm is put in front of a thermal emitter source to allow light of this wavelength to pass through. A CMOS compatible pyroelectric detector is put on the other end of the gas channel to measure the voltage change due to presence of SF6 gas. Here, we use AlN-based and 12% ScAlN-based pyroelectric detectors respectively. The results show for 100% SF6 gas sensing, 12% ScAlN-based pyroelectric detector gives ~73% higher response compared to when using AlN-based pyroelectric detector. The voltage drop between reference N2 gas and different SF6 gas concentrations is also higher (up to 2x) when using 12% ScAlN-based pyroelectric detector. Based on the measured SF6 gas responses, we try to estimate the lower limit of detection of our gas sensors when using AlN- and ScAlN- based pyroelectric detectors respectively. Response times taken for both detectors to detect SF6 concentrations are measured to be ~6.26 s for AlN-based pyroelectric detector and ~1.99 s for 12% ScAlNbased pyroelectric detector. Finally, both pyroelectric detectors’ electrical responses across different frequencies are measured and their 3-dB frequency cutoffs are extracted to be ~13.5 Hz and ~12.6 Hz for AlN- and 12% ScAlN- based pyroelectric detector respectively. The results provide more understanding on characteristics of pyroelectric detectors in SF6 greenhouse gas sensing based on mid-IR absorption.
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