A single exposure EUV patterning process has been optimized for hexagonal contact holes (CHs) at pitch 36nm and SRAM via. Defect inspection results are reported using after etch voltage contrast (VC) metrology as well as after metallization. By comparing top-down scanning electron microscopy (SEM) and VC images, the VC technique was proven to detect the close defective CHs not only on the top surface but also at the bottom of CHs. This is confirmed on cross section inspection using transmission electron microscopy (TEM) metrology. To quantify the number of defects (NoDs) per million CHs, both a greyscale analysis and a computer vision-based defect analysis algorithm are used and exhibits the dependence of NoDs on CHs mean CD. This algorithm is capable of detecting, classifying, and incrementally counting the occurrence of defect instances as closed, partially open and open CHs. An advantage of this algorithm is its distortion invariance and independence from GDS alignment.
One of the key steps in the pattern formation chain of extreme ultraviolet (EUV) lithography is the development process to resolve the resist pattern after EUV exposure. The traditional development process might be insufficient to achieve the requirements of ultra-high-resolution features with low defect levels. The aim of this paper is to establish a process to achieve a good roughness, a low defectivity at a low EUV dose, and capability for extremely-high-resolution for high numerical aperture (NA) and hyper-NA EUV lithography. A new development method named ESPERT™ (Enhanced Sensitivity develoPER Technology™) has been introduced to improve the performance of metal oxide-resists (MOR). ESPERT™ as a chemical super resolution technique effectively apodized the MOR chemical image, improving chemical gradient (higher exposure latitude (EL)) and reducing scums (fewer bridge defects). This new development method can also keep the resist profile vertical to mitigate the break defects. The performances of the conventional development and ESPERT™ were evaluated and compared using 0.33 NA EUV, 0.5 NA EUV, and electron beam (EB) exposures, for all line-space (LS), contact hole (CH), and pillar (PL) patterns. Using 0.33 NA EUV scanners on LS patterns, both bridge and break defects were confirmed to be reduced for all 32-nm-pitch, 28-nm-pitch, 26-nm-pitch LS patterns while reducing the EUV dose to size (DtS). In the electrical yield (1 meter length) test of breaks/bridges of 26-nm pitch structures, ESPERT™ reduced EUV dose while its combo yield was almost 100% over a wide dose range of 20mJ/cm². For CH patterns, in the case of 32-nm-pitch AEI (after etch inspection), EL was increased 7.5% up to 22.5%, while failure free latitude (FFL) was widened from 1-nm to 4-nm. A 16-nm-pitch LS pattern was successfully printed with 0.5 NA tool, while a 16-nm-pitch PL and an 18-nm-pitch CH patterns were also achieved with an EB lithography by ESPERT™. With ESPERT™, there was no pillar collapse observed for 12-nm half-pitch PL by 0.5 NA and 8-nm half-pitch PL by EB. With all the advantages of having a high exposure sensitivity, a low defectivity, and an extremely-high-resolution capability, this advanced development method is expected be a solution for high-NA EUV towards hyper-NA EUV lithography.
One of the key steps in the pattern formation chain of (extreme ultraviolet) EUV lithography is the development process to resolve the resist pattern after EUV exposure. A simple traditional development process might not be sufficient to achieve the requirements of an ultra-high-resolution feature with low defect levels in high numerical aperture (NA) EUV lithography. In our previous literature, a new development method named ESPERTTM (Enhanced Sensitivity develoPER TechnologyTM) has been introduced to improve the performance of metal oxide resists (MOR) for 0.33 NA EUV lithography by breaking the dose-roughness trade-off. In this work, this development technique was optimised for high-NA lithography to not only keep the advantages of previous ESPERTTM version, but also reduce the defect levels at a higher EUV sensitivity. This is made possible thanks to the capability of the new version of ESPERTTM that can easily remove the residue (undeveloped resist) at low exposure dose area to enhance the developing contrast. Using 0.33 NA EUV scanners at imec on 16-nm half-pitch (HP) line/space (L/S) patterns, with the new development method, EUV dose-to-size (DtS) was reduced roughly 16%, and total after-development-inspection (ADI) defects was reduced by a factor of approximately 7, simultaneously. In another condition, DtS was reduced from 44.2 to 28.4 mJ/cm² (an improvement of 36%), while the number of after-etch-inspection (AEI) single-bridge defects was reduced by half, simultaneously. Using the 0.5 NA exposure tool at Lawrence Berkeley National Laboratory with this new development method, the exposure sensitivity and line-width-roughness (LWR) were both improved by 30% and 21%, respectively. An 8-nm-HP L/S pattern was also successfully printed by this high NA tool. Using a 150 kV electron-beam (EB) lithography system, a 12-nm-HP of pillars was successfully printed on a 22-nm-thick MOR resist with ESPERTTM. With all the advantages of having a high exposure sensitivity, a low defectivity, and an ultra-high-resolution capability, this new development method is expected to be a solution for high-NA EUV lithography.
High-NA EUV lithography is currently under development to keep up with device node scaling with smaller feature sizes. In this paper, the most recent advances in EUV patterning using metal oxide resists (MOR) and chemically amplified resists (CAR) are discussed. A newly developed resist development method (ESPERT™) was examined on MOR with 24 nm pitch line and space (L/S) patterns and 32 nm pitch pillars for preparation of high-NA EUV patterning. The patterning results showed improved sensitivity and pattern collapse margin. CAR contact hole patterning at 28 nm pitch was also examined by stochastic lithography simulation. The simulation results indicate that resist film thickness needs to be optimized for target pitches.
EUV (extreme ultraviolet) lithography has been introduced in high volume manufacturing in 2019 and continuous improvements have allowed to push the lithographic performance to the limits of 0.33 NA single exposure. However, stochastic failures, pattern roughness and local critical dimension uniformity (LCDU) are still major challenges that need to be addressed to maintain node shrinkage and improve yield. Together with pitch downscaling, photoresist thickness is decreasing to prevent pattern collapse. A lower depth of focus is also expected with high NA EUV which might even thin further down the resist layer. Being able to transfer the patterns with good fidelity is therefore getting very challenging because the resist “etch budget” is becoming too small to prevent pattern break during plasma etch transfer. A co-optimization of lithography processes, underlayers coating and etch processes is essential to further support the EUV patterning extension.
In this report, recently developed hardware and process solutions to stretch the limits of EUV patterning will be presented. The latest performance for both chemically amplified resists (CAR) and metal oxide resists (MOR) will be introduced, with a focus on defect mitigation, dose reduction strategies and CD stability.
In 2021 IRDS logic roadmap, required minimum contact/via pitch is 28 nm in 2025, which cannot be obtained by single exposure at 0.33 NA system using chemical amplified resist (CAR). To make the target possible, 0.55 NA system is the only way for single exposure. The relationship of resolution, roughness, and sensitivity has been known to be trade-off in CAR, and we tried optimizing them at 0.55 NA lithography simulation. For the optimization, not only resist material parameters, but also resist development parameters were adjusted. In addition, we conducted numerical simulation for line and space (L/S) pattern of metal oxide resist (MOR), which is expected as one of the breakthroughs for making narrower patterns. We set up a MOR NTD model and calibrated it by experimental data. The calibrated model is applied to the evaluation of the patterning performance including dose to size (DtS), roughness, and resist profile. Simulation results regarding a new wet development method for MOR to break through the RLS trade-off are introduced.
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